Why does iron ore mining need water?
For magnetite mining, water is used
in ore processing, to increase the quality and concentration of iron.
After crushing, the dry ore is mixed with water and wet screened. This allows
the ore to be directly fed into a steel pellet plant without further treatment.
Some operations also use water to transport the ore via a slurry
pipeline. Importantly, a significant amount of the water used in processing and
transport is recycled.
Waste Characteristics
In certain mines with ores with high
sulfur content, drainage from mine workings and waste heaps can become highly
acidic and contain dissolved high concentrations of heavy metals. This Acid
Mine Drainage (AMD) can have a pH of 3 or lower; sulfate levels of 800-1800
milligrams per liter (mg/L); copper levels up to 50 milligrams per liter
(mg/L); iron levels up to 1000 milligrams per liter (mg/L); lead levels up to
12 milligrams per liter (mg/L); zinc levels up to 1700 mg/L, and cadmium levels
of several milligrams per liter depending on the contents of the ore. The
tailings pond effluent may also contain concentrations of chromium of several
milligrams per liter. Base metal mining tailings decant may also contain high
concentrations of thiosalts. Chemicals used in metal concentration (floatation
and other) processes could also pose toxicity when released in effluents.
Surface runoffs may also pose
significant environmental problems through erosion and carry-over of tailings
and other mining residues. Explosives, such as ammonium nitrate, may also be
present in surface runoff. Contamination of surface water can also occur from
transport of mined material and from machinery maintenance and repair.
Significant levels of dust, above to
3 kilogram per ton (kg/t) (with a range of 0.003 to 27 kg/t) of ore mined, may
be generated. This dust can be generated by extraction activities, crushing,
ore beneficiation, transportation and traffic, and by wind borne losses.
Significant releases of metal (including mercury) containing dust may result
from the drying of the ore concentrate.
Process
Iron ore is converted into various types of iron through several processes.
The most common process is the use of a blast furnace to produce pig iron which
is about 92-94% iron and 3-5% carbon with smaller amounts of other elements.
Pig iron has only limited uses, and most of this iron goes on to a steel mill
where it is converted into various steel alloys by further reducing the carbon
content and adding other elements such as manganese and nickel to give the
steel specific properties.
Extraction
Extraction
Refining
- The
mined ore is crushed and sorted. The best grades of ore contain over 60%
iron. Lesser grades are treated, or refined, to remove various
contaminants before the ore is shipped to the blast furnace. Collectively,
these refining methods are called beneficiation and include further
crushing, washing with water to float sand and clay away, magnetic
separation, pelletizing, and sintering. As more of the world's known
supply of high iron content ore is depleted, these refining techniques
have become increasingly important.
- The
refined ore is then loaded on trains or ships and transported to the blast
furnace site.
The Manufacturing Process
Charging the blast furnace
- After
processing, the ore is blended with other ore and goes to the blast
furnace. A blast furnace is a tower-shaped structure, made of steel, and
lined with refractory, or heat-resistant bricks. The mixture of raw
material, or charge, enters at the top of the blast furnace. At the bottom
of the furnace, very hot air is blown, or blasted, in through nozzles
called tuye'res. The coke burns in the presence of the hot air. The
oxygen in the air reacts with the carbon in the coke to form carbon
monoxide. The carbon monoxide then reacts with the iron ore to form carbon
dioxide and pure iron.
Separating the iron from the slag
- 2 The
melted iron sinks to the bottom of the furnace. The limestone combines
with the rock and other impurities in the ore to form a slag which is
lighter than the iron and floats on top. As the volume of the charge is
reduced, more is continually added at the top of the furnace. The iron and
slag are drawn off separately from the bottom of the furnace. The melted
iron might go to a further alloying process, or might be cast into ingots
called pigs. The slag is carried away for disposal.
Treating the gases
- 3 The
hot gases produced in the chemical reactions are drawn off at the top and
routed to a gas cleaning plant where they are cleaned, or scrubbed, and
sent back into the furnace; the remaining carbon monoxide, in particular,
is useful to the chemical reactions going on within the furnace.
A blast
furnace normally runs day and night for several years. Eventually the brick
lining begins to crumble, and the furnace is then shut down for maintenance.
Byproducts/Waste
There are a great many possible environmental
effects from the iron industry. The first and most obvious is the process of
open pit mining. Huge tracts of land are stripped to bare rock. Today, depleted
mining sites are commonly used as landfills, then covered over and landscaped.
Some of these landfills themselves become environmental problems, since in the
recent past, some were used for the disposal of highly toxic substances which
leached into soil and water.
The process of extracting iron from ore
produces great quantities of poisonous and corrosive gases. In practice, these
gases are scrubbed and recycled. Inevitably, however, some small amounts of
toxic gases escape to the atmosphere.
A byproduct of iron purification is slag,
which is produced in huge amounts. This material is largely inert, but must
still be disposed of in landfills.
Iron making uses up huge amounts of coal. The
coal is not used directly, but is first reduced to coke which consists of
almost pure carbon. The many chemical by products of coking are almost all
toxic, but they are also commercially useful. These products include ammonia,
which is used in a vast number of products; phenol, which is used to make
plastics, cutting oils, and antiseptics; cresols, which go into herbicides,
pesticides, pharmaceuticals, and photographic chemicals; and toluene, which is
an ingredient in many complex chemical products such as solvents and
explosives.
Scrap iron and steel—in the form of old cars,
appliances and even entire steel-girdered buildings—are also an environmental
concern. Most of this material is recycled, however, since steel scrap is an
essential resource in steel making. Scrap which isn't recycled eventually turns
into iron oxide, or rust, and returns to the ground.
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